Engineering
Chemistry
Electrolytic Conductance
Question

A graph was plotted between the molar conductance of various electrolytes (HCl, KCl and CH3COOH) and root of their concentrations in mole per litre.

Which of the following is correct match?

I (CH3COOH) ; II (HCl) ; III (KCl)

I (KCl) ; II (CH3COOH) ; III (HCl)

I (CH3COOH) ; II (KCl) ; III (HCl) 

I (HCl) ; II (KCl) ; III (CH3COOH)

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Solution

Molar conductance of HCl will be maximum and CH3COOH will be minimum because

(i)     [H+] have exceptional ionic mobility
(ii)    CH3COOH is a weak electrolyte