Engineering
Chemistry
Auto Ionization of Water

Question

An acid-base titration consists of the controlled adding of a dissolved base to a dissolved acid (or the reverse). Acid-base react rapidly to neutralize each other. At the equivalence point, enough titrant, the solution being added, has gone into make the chemical amounts of the acid and base exactly equal.

The pH of a titration changes every time a drop of titrant is added, but the rate of this change varies enormously. A titration curve, graph of pH as a function of the volume of titrant, displays in detail how the pH changes over the course of an acid-base titration. Significantly, the pH changes most rapidly near the equivalence point. The exact shape of a titration curve depends on the Ka and Kb acid and base.

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Linked Question 1

In the titration curve of HCl against NaOH, the pH equivalence point will be :

3

8

6

7

Solution
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Verified by Zigyan

SA and SB titration equivalence point is always 7 because SASB salt have no hydrolysis 

Linked Question 2

Which of the following curves indicates the titration of a weak diprotic acid by NaOH of equivalent

  

  

  

  

Solution
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Verified by Zigyan

H2A + NaOH → NaHA + H2O              first equivalence point

pH = pKa1+pKa12 

NaOH + NaHA → Na2A + H2O            second equivalence point

pH = 7+12pKa2+12 log C

sharp changes should be there at each equivalence point.

Linked Question 3

   

Which of the titrations also could it represent ?

HCl by NaOH

HCl by KOH

NH3 by HNO3 

RbOH by HBr

Solution
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Verified by Zigyan

If RbOH is titrated by HBr(SA) then curve goes down but if HBr is titrated by RbOH then curve goes up.