A three-center two-electron bond is an electron deficient chemical bond where three atoms share two electrons. The combination of three atomic orbitals form three molecular orbital s : one bonding, one non-bonding, and one anti-bonding.

The two electrons go into the bonding orbital, resulting in a net bonding effect and constituting a chemical bond among all three atoms. In many common bonds of this type, the bonding orbital is shifted towards two of the three atoms instead of being spread equally among all three. The simplest example of a 3c – 2e bond is in the B₂H₆. Hence correct answer is option D.