Engineering
Chemistry
Aromaticity

Question

Aromatic compounds are those that meet the following criteria:
(i)    The structure must be cyclic, containing conjugated system.
(ii)    Each atom in the ring must have an unhybridized p orbital. (The ring atoms are usually sp2 hybridised )  
(iii)    The unhybridised p orbitals must overlap to form a continuous ring of parallel orbitals. In most cases, the structure must be planar (or nearly planar) for effective overlap to occur.
(iv)    Delocalization of the π electrons over the ring must lower the electronic energy.
An antiaromatic compound is one that meets the first three criteria, but delocalization of the π electrons over the ring increases the electronic energy.   

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Linked Question 1

Which of the following is aromatic compound?

 

Solution

6πe         Aromatic

Linked Question 2

Which of the following is anti-aromatic compound.

None of these

Solution

Nonaromatic     

4πe Antiaromatic       

Nonaromatic

Linked Question 3

In which of the following reaction product is aromatic?

All of these 

Solution