Aromatic compounds are those that meet the following criteria:
(i) The structure must be cyclic, containing conjugated system.
(ii) Each atom in the ring must have an unhybridized p orbital. (The ring atoms are usually sp2 hybridised )
(iii) The unhybridised p orbitals must overlap to form a continuous ring of parallel orbitals. In most cases, the structure must be planar (or nearly planar) for effective overlap to occur.
(iv) Delocalization of the π electrons over the ring must lower the electronic energy.
An antiaromatic compound is one that meets the first three criteria, but delocalization of the π electrons over the ring increases the electronic energy.
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Which of the following is anti-aromatic compound.
Nonaromatic
4πe– Antiaromatic
Nonaromatic
Which of the following is aromatic compound?
6πe– Aromatic
In which of the following reaction product is aromatic?
