Engineering
Chemistry
Heating effect
Aldol condensation
Cannizzaro reaction
Question

Complete reaction of acetaldehyde with excess formaldehyde, upon heating with conc. NaOH solution, gives P and Q. Compound P does not give Tollens’ test, whereas Q on acidification gives positive Tollens’ test. Treatment of P with excess cyclohexanone in the presence of catalytic amount of p-toluenesulfonic acid (PTSA) gives product R.
Sum of the number of methylene groups (–CH2–) and oxygen atoms in R is ______.

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Solution

Total CH2 in R = 14
and oxygen in R= 4
So 14 + 4 = 18