Engineering
Chemistry
Bond Length and Bond Angle Comparison
Question

Correct order of PH bond length and PO bond order in 

P–O bond order of H2PO2–1 < HPO3–2 and P–H bond length H2PO2–1 < HPO3–2

P–O bond order of H2PO2–1 > HPO3–2 and P–H bond length H2PO2–1 > HPO3–2 

P–O bond order of H2PO2–1 < HPO3–2 and P–H bond length H2PO2–1 > HPO3–2

P–O bond order of H2PO2–1 > HPO3–2 and P–H bond length H2PO2–1 < HPO3–2

JEE Advance
College PredictorLive

Know your College Admission Chances Based on your Rank/Percentile, Category and Home State.

Get your JEE Main Personalised Report with Top Predicted Colleges in JoSA

Solution

                                     32=1.5                >                  43=1.33

(P–O) Bond order    

P–H  bond length                                >

(P–O)     Bond order (H2PO2¯) ­ , %s in (P–O)­ , %s in (P–H) so Bond length in (H2PO2¯) is greater than HPO3–2