Engineering
Chemistry
Electrolysis
Faraday Law
Extraction of Iron and Copper
Question

During the extraction of aluminium by Hall-He'roult process,
(i) Write a neat labeled diagram of the electrolytic cell.
(ii) Write over all cell reaction.
(iii) At which electrode oxygen gas is liberated?

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Solution
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During the extraction of aluminium by Hall-He'roult process,
(i) Neat labelled diagram of electrolytic cell is as shown.
(ii) Over all cell reaction is 2Al2O3+3C4Al+3CO2.

(iii) At anode oxygen gas is liberated.
C + O2– → CO + 2e
C + 2O2– → CO2 + 4e
At cathode, Al is obtained.
Al3+ + 3e → Al