Engineering
Chemistry
Resonance and Bond Order
Question

For the compounds CH3Cl, CH3Br, CH3I and CH3F, the correct order of increasing C-halogen bond length is:

CH3F < CH3Br < CH3Cl < CH3I

CH3F < CH3Cl < CH3Br < CH3I

CH3F < CH3l < CH3Br < CH3Cl

CH3Cl < CH3Br < CH3F < CH3I

JEE Advance
College PredictorLive

Know your College Admission Chances Based on your Rank/Percentile, Category and Home State.

Get your JEE Main Personalised Report with Top Predicted Colleges in JoSA

Solution

C-halogen bond length totally depends on the electronegativity difference between Carbon and halogen. The more the difference is, the less is the bond length. The electronegativity order of halogens is I < Br < Cl < F. Hence, the correct order of increasing C-halogen bond length is CH3F < CH3Cl < CH3Br < CH3I.

Hence, the correct option is (A)