Engineering
Chemistry
Oxidation of alcohol

Question

Generally alcohols give alkene on dehydration. Various dehydrating agents can be used for this purpose like conc. H2SO4, H3PO4, KHSO4 etc. When these dehydrating agents are used, carbocation generate during reaction. Generation of carbocation is rate determining step. Rearrange products are also formed during reaction. Generally Seytzeff alkene forms as major alkene. Example :

 

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Linked Question 1

How many alkenes will form during Dehydration of cyclooctanol?

3

2

4

1

Solution
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Linked Question 2

How many 1,2-shifting are involved during formation of given product in following reaction?

 

3

1

2

4

Solution
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Linked Question 3

What will be order of rate of dehydration for following alcohols?

 

III > II > I

III < II < I

I > III > II

I > II > III

Solution
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Rate of dehydration a Stability of carbocation