Engineering
Chemistry
Ellingham Diagram
Question

If ΔG vs T graph of 

I → 43 Al + O→ 23 Al2O3

II  →     2Mg + O2 → 2MgO
is given as below :

Then ΔG vs T graph of reaction 
III  3Mg + Al2O3  3MgO + 2Al   
IV  3MgO + 2Al  3Mg + Al2O3
are:

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Solution

at T < 1400°C        at  T > 1400°C

III  3Mg + Al2O3  3MgO + 2Al   G < 0      G > 0
IV  3MgO + 2Al  3Mg + Al2O3     G > 0   G < 0