Engineering
Chemistry
Vander Waal Gas and compressibility Factor
Liquefaction and Critical Temperature Pressure and Volume
Pressure Volume and Temperature
Question
Isotherms of a real gas is represented as shown in diagram at three temperature T1, T2, T3. From the graph, predict in which case gas-liquid transition will involve only one phase throughout.
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Solution
ADEG and BADE involve two phase equilibrium along DE
BCI involves no phase transition,
In, ACIH ⇒ at A, C, I only gaseous phase
Just above point H ⇒ Gaseous phase
Just below point H ⇒ Liquid phase