Engineering
Chemistry
Atomic and Ionic Radius
VSEPR Theory
Hybridisation
Question

The correct order of increasing s-character (in percentage) in the hybrid orbitals of following molecules and ions is 
(I) CO32–  (II) XeF4 (III) I3  (IV) NCI3 (V) BeCI2

II < III < IV < I < V

II < III < IV < V < I

III < II < I < V < IV

II < IV < III < I < V

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Solution
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More is the percentage of s – character in a compound more nile be the electronegativity of central metal atom.
The hybridization of given compound will be as follows:–

  • CO32– has hybridisation of SP2
  • xef4 has hybridisation of sp3d2
  • I3– has hybridisation of s3d
  • Nal3 has hybridisation of SP3
  • BeCl2 has hybridisation of Sp as it has linear geometry.
    Lesser is the no. of porbital, more mill be percentage of scharacter.
    Hence correct increasing order of s-character is:–

xeFI– NClCO32–BeCl2

Thus we can conclude that correct order of increasing s – character is:

 II < III < IV V

Option (A) is correct