Engineering
Chemistry
Halogenation of aromatic compounds
Question

The reaction of toluene with Cl2 in presence of Fe, the product(s) formed is/are:

o- and p-chlorotoluene
benzyl chloride
m-chlorotoluene
only p-chlorotoluene
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Solution

– CH3 group on benzene is ortho and para directing. 

In presence of Cl, it forms ortho (minor) and para (major) chlorotoluene as products.
Option A is correct.