Engineering
Chemistry
First Law and Various Process
Enthalpy and Internal Energy Relation
Gibbs Free Energy Entropy and Spontaneity
Question

ΔU° of combustion of methane is −X kJ mol−1. The value of ΔH° is:

= 0

> ΔUº

< ΔUº

= ΔUº

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Solution
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Correct option is C) Reaction;

CH4(g) + 2O2(g) → CO2(g) + 2H2O(l)

Now, Δng = (n− nr) = 1 − 3 = −2

Again ΔHº = ΔUº  + ΔngRT

ΔHº = − X − 2RT

∴  ΔHº  < ΔU°