What happens when: manganese dioxide is heated with aluminium powder ?
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When manganese dioxide (MnO2) is heated with aluminium powder, displacement reaction takes place, and manganese is obtained as the product along with aluminium oxide. It is an exothermic reaction and hence Mn is obtained in molten form.
3MnO2(s) + 4Al(s) → 3Mn(l) + 2Al2O3(s) + heat